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Poly­[[[aqua­manganese(II)]-2-4,4′-bi­pyridine-3-succinato] 4,4′-bi­pyridine hemisolvate]

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Abstract:

The polymeric title complex, {[Mn(C4H4O4)(C10H8N2)(H2O)]·0.5C10H8N2}n, possesses a three-dimensional open-framework structure, with the solvate 4,4′-bi­pyridine (bipy) mol­ecules, which lie around centers of inversion, clathrated in the channels of the framework. The MnII center is surrounded by three succinate (succ) ligands, one water mol­ecule and two bipy ligands, and displays a slightly distorted octahedral coordination environment, with cis angles ranging from 84.14 (12) to 96.56 (11)°. Each succ dianion coordinates to three MnII atoms, thus acting as a bridging tridentate ligand; in turn, the MnII atoms are bridged by three succ ligands, thus forming a two-dimensional Mn–succ sheet pillared by the bridging bipy ligands. Two hydrogen-bonding interactions, involving the water mol­ecules and the carboxy O atoms of the succ ligands, are present in the crystal structure.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104009953

Publication date: June 1, 2004

bsc/ayc/2004/00000060/00000006/art00022
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