Skip to main content

Poly­[[[aqua­manganese(II)]-2-4,4′-bi­pyridine-3-succinato] 4,4′-bi­pyridine hemisolvate]

Buy Article:

$51.00 plus tax (Refund Policy)


The polymeric title complex, {[Mn(C4H4O4)(C10H8N2)(H2O)]·0.5C10H8N2}n, possesses a three-dimensional open-framework structure, with the solvate 4,4′-bi­pyridine (bipy) mol­ecules, which lie around centers of inversion, clathrated in the channels of the framework. The MnII center is surrounded by three succinate (succ) ligands, one water mol­ecule and two bipy ligands, and displays a slightly distorted octahedral coordination environment, with cis angles ranging from 84.14 (12) to 96.56 (11)°. Each succ dianion coordinates to three MnII atoms, thus acting as a bridging tridentate ligand; in turn, the MnII atoms are bridged by three succ ligands, thus forming a two-dimensional Mn–succ sheet pillared by the bridging bipy ligands. Two hydrogen-bonding interactions, involving the water mol­ecules and the carboxy O atoms of the succ ligands, are present in the crystal structure.

Document Type: Research Article


Publication date: June 1, 2004


Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more