Bis(-1,10-phenanthrolin-2-olato-3N,N′:O)­dicopper(I)(Cu—Cu) monohydrate

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The crystal structure of the title compound, [Cu2(C12H7­N2O)2]·H2O, shows that this dinuclear complex has shorter Cu—N, Cu—O and Cu—Cu distances within the coordination sphere than similar reported complexes. The complex mol­ecule is located on a centre of symmetry and the water mol­ecule is on a twofold axis of the space group C2/c. The discrete complex mol­ecules are extended into a two-dimensional supramolecular array via– stacking interactions, intermolecular Cu…Cu interactions and C—H…O hydrogen bonds.

Document Type: Research Article


Publication date: June 1, 2004

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