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Poly­[[di­aqua­tris(6-benzene-1,2,4,5-tetra­carboxyl­ato)­tris(2-4,4′-bi­pyridine)­hexacopper(II)] dihydrate]

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The hydro­thermal reaction of an aqueous solution of Cu(CH3COO)2·H2O, 1,2,4,5-benzene­tetra­carboxylic acid and 4,4′-bi­pyridine gave rise to the interesting title three-dimensional polymer {[Cu6(btec)3(4,4′-bpy)3(H2O)2]·2H2O}n (btec is 1,2,4,5-benzene­tetra­carboxyl­ate, C10H2O84−, and 4,4′-bpy is 4,4′-bi­pyridine, C10H8N2), in which each btec ligand links six copper(II) cations into a lamellar [Cu6(btec)3(H2O)2]n sub­polymer framework. There are two distinct diamine units and two distinct carboxylate units, with one of each lying across an inversion centre.

Document Type: Research Article


Publication date: 2004-06-01

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