(1R,2R)-(–)-Bis­[4-1-{[1,1-di­methyl-2-(tri­methyl­silyl)­amidino]­amino}-2-({1,1-di­methyl-2-[1,1-di­methyl-2-(tri­methyl­silyl)­amidino]­amidino}amino)cyclo­hexane]­tetralithium(I)

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Abstract:

The title compound, [Li4(C21H46N8Si2)2], has been prepared and its structure determined. The whole mol­ecule can be regarded as a molecular cage made up of the central eight-membered ring and six contiguous rings of three types. As the first example of a bridged amidinate–dicyan­amide framework, this noteworthy structure and its electronic features are presented.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104008509

Publication date: June 1, 2004

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