A one-dimensional double-chain coordination polymer: [Mn(C12H13NO6S)(C10H8N2)]n
Abstract:In the title compound, poly[[(2,2′-bipyridine-2N,N′)manganese(II)]-3-N-tosyl-l-glutamato-4O,O′:O′′:O′′′], [Mn(tsgluo)(bipy)]n, where tsgluo is N-tosyl-l-glutamate (C12H13NO6S) and bipy is 2,2′-bipyridine (C10H8N2), the Mn atoms are octahedrally coordinated by two N atoms of one bipy ligand and by four O atoms of three tsgluo2− anions. The -carboxyl group coordinates to the MnII atom in a chelating mode, while the α-carboxyl group coordinates in a bidentate–bridging mode. The complex displays a one-dimensional double-chain structure.
Document Type: Research Article
Publication date: June 1, 2004