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A one-dimensional double-chain coordination polymer: [Mn(C12H13NO6S)(C10H8N2)]n

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Abstract:

In the title compound, poly­[[(2,2′-bi­pyridine-2N,N′)­manganese(II)]-3-N-tosyl-l-glutamato-4O,O′:O′′:O′′′], [Mn(tsgluo)(bipy)]n, where tsgluo is N-tosyl-l-glutamate (C12H13NO6S) and bipy is 2,2′-bi­pyridine (C10H8N2), the Mn atoms are octahedrally coordinated by two N atoms of one bipy ligand and by four O atoms of three tsgluo2− anions. The -carboxyl group coordinates to the MnII atom in a chelating mode, while the α-carboxyl group coordinates in a bidentate–bridging mode. The complex displays a one-dimensional double-chain structure.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104008893

Publication date: June 1, 2004

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