cis-Di­phenyl­bis(1,3,5-tri­aza-7-phospha­adamantane-κP)platinum(II)

Authors: Muller, Alfred; Roodt, Andreas

Source: Acta Crystallographica Section C, Volume 60, Number 6, June 2004 , pp. m266-m268(3)

Publisher: Wiley-Blackwell

Abstract:

The structure of the title compound, [Pt(C₆H₅)₂(C₆H₁₂N₃P)₂] or [Pt(Ph)₂(PTA)₂] (where Ph is phenyl and PTA is 1,3,5-tri­aza-7-phosphaadamantane), is discussed. Selected geom­etric parameters are: Pt—P = 2.2888 (16) and 2.2944 (17) Å, Pt—C = 2.052 (5) and 2.064 (6) Å, C—Pt—C = 84.6 (2)° and P—Pt—P = 99.28 (6)°. The effective cone angle for the PTA ligands was calculated as 113°.

Document Type: Research article

DOI: http://dx.doi.org/10.1107/S0108270104009096

Publication date: 2004-06-01

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