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cis-Di­phenyl­bis(1,3,5-tri­aza-7-phospha­adamantane-P)platinum(II)

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Abstract:

The structure of the title compound, [Pt(C6H5)2(C6H12N3P)2] or [Pt(Ph)2(PTA)2] (where Ph is phenyl and PTA is 1,3,5-tri­aza-7-phosphaadamantane), is discussed. Selected geom­etric parameters are: Pt—P = 2.2888 (16) and 2.2944 (17) Å, Pt—C = 2.052 (5) and 2.064 (6) Å, C—Pt—C = 84.6 (2)° and P—Pt—P = 99.28 (6)°. The effective cone angle for the PTA ligands was calculated as 113°.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104009096

Publication date: June 1, 2004

bsc/ayc/2004/00000060/00000006/art00015
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