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Polymeric (2-nitrato-2O:O′)(2-nitrato-2O:O)(4-pyridinium-4-thiol­ato-4S:S:S:S)­disilver(I)

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The title compound, [Ag2(NO3)2(C5H5NS)]n, was obtained from the reaction of silver nitrate with bis(4-pyridyl) disufide (4-PDS) in a mixture of ethanol and water, which suggests that the di­sulfide bond of 4-PDS can be cleaved under mild conditions. The structure of the title compound is a two-dimensional infinite array in which the asymmetric unit contains two Ag atoms, a pyridinium-4-thiol­ate mol­ecule and two nitrate groups. Each pyridinium-4-thiol­ate mol­ecule acts as a 4 bridge, linking four Ag atoms, with Ag—S bond distances of 2.4870 (19), 2.5791 (19), 2.5992 (19) and 2.848 (2) Å. The Ag…Ag distances lie in the range 2.889 (2)–3.049 (1) Å.
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Document Type: Research Article

Publication date: 2004-06-01

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