The title compound, [Fe(C9H10BN6)2]3[Fe(NCS)6] or [FeIII(Tp)2]3[FeIII(NCS)6] [Tp is hydrotris(1-pyrazolyl)borate], crystallizes in space group ; the asymmetric unit comprises one-half of an [Fe(Tp)2]+ cation, with its Fe atom on a crystallographic inversion centre, and one-sixth of an [Fe(NCS)6]3− anion, on a site of symmetry. The anions and cations are stacked into a three-dimensional supramolecular aggregate via two distinct types of weak C—H… interactions.
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Document Type: Research Article
Publication date: 2004-06-01