Pentaethyl­enehex­amine­manganese(II) pentaborate

Authors: Zhang, Hong-Xia; Zheng, Shou-Tian; Yang, Guo-Yu

Source: Acta Crystallographica Section C, Volume 60, Number 6, June 2004 , pp. m241-m243(3)

Publisher: Wiley-Blackwell

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The title compound, (pentaethylenehexamine-6N)manganese(II) 4,4′,6,6′-tetrahydroxy-2,2′-spirobi(cyclotriboroxane)(1−), [Mn(C10H28N6)][B5O6(OH)4]2, was synthesized under mild solvothermal conditions. The B5O6(OH)4 units are connected to one another via hydrogen bonds, forming a three-dimensional framework with large channels along the a and c axes, in which the templating [Mn(C10H28N6)]2+ cations are located. The MnII complex cation has a twofold axis and the coordination geometry of the MnN6 group is that of a distorted trigonal prism.

Document Type: Research Article


Publication date: June 1, 2004

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