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Pentaethyl­enehex­amine­manganese(II) pentaborate

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Abstract:

The title compound, (pentaethylenehexamine-6N)manganese(II) 4,4′,6,6′-tetrahydroxy-2,2′-spirobi(cyclotriboroxane)(1−), [Mn(C10H28N6)][B5O6(OH)4]2, was synthesized under mild solvothermal conditions. The B5O6(OH)4 units are connected to one another via hydrogen bonds, forming a three-dimensional framework with large channels along the a and c axes, in which the templating [Mn(C10H28N6)]2+ cations are located. The MnII complex cation has a twofold axis and the coordination geometry of the MnN6 group is that of a distorted trigonal prism.

Document Type: Research Article

DOI: https://doi.org/10.1107/S0108270104007942

Publication date: 2004-06-01

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