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cis-Dinitrito(1,4,8,11-tetra­aza­cyclo­tetra­decane-4N)­chromium(III) nitrite

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Abstract:

In the title compound, [Cr(ONO)2(cyclam)]NO2 (cyclam is 1,4,8,11-tetra­aza­cyclo­tetra­decane, C10H24N2), the complex cation is located on a twofold symmetry axis. The central Cr atom has a distorted octahedral coordination, involving two Cr—O bonds, with the monodentate nitrite O atoms adopting a cis configuration, and four Cr—N bonds. The mean Cr—N and Cr—O distances are 2.0895 (14) and 1.9698 (14) Å.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104007656

Publication date: June 1, 2004

bsc/ayc/2004/00000060/00000006/art00005
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