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Dibarium zirconium tetraoxalate trihydrate

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Abstract:

A new mixed barium zirconium oxalate, tri­aqua­tetra--oxalato-dibarium(II)­zirconium(IV), Ba2Zr(C2O4)4·3H2O or [Ba2Zr(C2O4)4(H2O)3]n, has been synthesized. The complex is built from eightfold-coordinated Zr atoms and eleven- and sixfold-coordinated Ba atoms, linked by oxalate groups. The Zr atom, the two Ba atoms and one water O atom lie on crystallographic twofold axes, so that each coordination polyhedron has imposed C2 symmetry. Packing in the crystal is also assumed through hydrogen bonds.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104006791

Publication date: June 1, 2004

bsc/ayc/2004/00000060/00000006/art00003
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