Skip to main content

Cs2Mo15S19: a novel ternary reduced molybdenum sulfide containing Mo6 and Mo9 clusters

Buy Article:

$51.00 plus tax (Refund Policy)

Abstract:

The crystal structure of dicaesium pentadecamolybdenum nonadeca¬≠sulfide, Cs2Mo15S19, consists of a mixture of Mo6S8S6 and Mo9S11S6 cluster units in a 1:1 ratio. Both units are interconnected via inter-unit Mo—S bonds. The Cs+ cations occupy large voids between the different cluster units. The Cs and two inner S atoms lie on sites with 3 symmetry (Wyckoff site 12c) and the Mo and S atoms of the median plane of the Mo9S11S6 cluster unit on sites with 2 symmetry (Wyckoff site 18e).

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104008248

Publication date: June 1, 2004

bsc/ayc/2004/00000060/00000006/art00001
dcterms_title,dcterms_description,pub_keyword
6
5
20
40
5

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more