Tris(2-pyridyl)­phosphine oxide: how C—H⃛O and C—H⃛N interactions can affect crystal packing efficiency

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Abstract:

Tris(2-pyridyl)­phosphine oxide, (I), C15H12N3OP, is isomorphous with tris(2-pyridyl)­phosphine. Because of a combination of C—H…O and C—H…N interactions, the crystal packing is denser in the title compound than in the related compounds tri­phenyl­phosphine oxide and tris(2-pyridyl)­phosphine.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104003956

Publication date: April 1, 2004

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