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Azido­[1,1′-bis­(di­phenyl­phosphino)­ferrocene](penta­methyl­cyclo­penta­dienyl)­rhodium(III) hexa­fluoro­phosphate

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In the title compound, azido-2N-bis­[-(15:2P)-di­phenyl­phosphino­cyclo­penta­dienyl][2(5)-penta­methyl­cyclo­penta­di­enyl]­iron(III)­rhodium(III) hexa­fluoro­phosphate, [{Rh(C10H15)(N3)}{Fe(-C17H14P)2}]PF6 or [FeRh(C10H15)(-C17H14P)2(N3)]PF6, the coordination sphere of RhIII can be described as pseudo-tetrahedral, composed of two P atoms from a 1,1′-bis­(di­phenyl­phosphino)­ferrocene (dppf) ligand, an azido N atom and the centroid of the ring of a C5Me5 (Cp*) ligand. The two cyclo­penta­dienyl rings in the dppf moiety adopt an eclipsed conformation. The Rh…Fe distance is 4.340 (2) Å.
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Document Type: Research Article

Publication date: 2004-04-01

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