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{Tris[4-(1H-pyrazol-3-yl)-3-azabut-3-enyl]­amine}­iron(II) diperchlorate monohydrate

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Abstract:

In the title complex, [Fe(C18H24N10)](ClO4)2·H2O, the com­plex cation adopts a capped trigonal antiprismatic stereochemistry, with a long Fe–amine interaction [2.7468 (16) Å]. The Fe centre in the asymmetric unit is fully high-spin at 100 K. Hydro­gen bonding assembles dimeric units, which are then linked by further hydrogen bonding into chains running parallel to the crystallographic a axis.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S010827010400407X

Publication date: April 1, 2004

bsc/ayc/2004/00000060/00000004/art00018
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