-Ethane-1,2-diyl­bis­(di­phenyl­phos­phine oxide)-2O:O′-bis­[di­benzyl­dichloro­tin(IV)]: a centrosymmetric complex containing trigonal-bipyram­idal tin(IV), linked into chains of rings by C—H⃛(arene) hydrogen bonds

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Abstract:

The title compound, [Sn2Cl4(C7H7)4(C26H24O2P2)], (I), was isolated from the reaction of 1,2-bis­(di­phenyl­phosphino)­ethane with di­benzyl­tin(IV) dichloride in the presence of air. The mol­ecules of (I) lie across centres of inversion in space group C2/c and contain five-coordinate Sn atoms. The mol­ecules are linked into chains of rings by a single C—­H…(arene) hydrogen bond.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104003981

Publication date: April 1, 2004

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