catena-Poly­[[di­chlorozinc(II)]--1,3-di-4-pyridyl­propane-2N:N′]

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Abstract:

The title compound, [ZnCl2(bpp)]n (where bpp is 1,3-di-4-pyridyl­propane, C13H14N2), has been prepared by the hydro­thermal reaction of ZnCl2 and bpp at 433 K. The Zn, Cl and central propyl C atom lie on the mirrors of the P21/m space group. The molecular structure shows a weave-like polymeric chain. Each Zn atom is coordinated by two N atoms and two Cl atoms in a distorted tetrahedral geometry, with the Zn—N distance being 2.055 (5) Å and the Zn—Cl distances being 2.239 (3) and 2.247 (2) Å.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104003592

Publication date: April 1, 2004

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