(2,2′-Bi­pyridine-2N,N′)(2,3-naph­tha­lene­diolato-2O,O′)­palladium(II) and (2,2′-bi­quinoline-2N,N′)(2,3-naph­thal­ene­diolato-2O,O′)­palladium(II)

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Abstract:

In the title compounds, [Pd(C10H6O2)(C10H8N2)], (I), and [Pd(C10H6O2)(C18H12N2)], (II), each PdII atom has a similar distorted cis-planar four-coordination geometry involving two O atoms of the 2,3-­naphthalenediolate dianion and two N atoms of the 2,2′-bi­pyridine or 2,2′-bi­quinoline ligand. The overall structure of (I) is essentially planar, but that of (II) is not, as a result of intramolecular overcrowding leading to bowing of the bi­quinoline ligand.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104002690

Publication date: April 1, 2004

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