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Hydrates of tin tetrachloride

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The crystal structures of the tri- and tetrahydrate of tin tetrachloride, viz. diaquatetrachlorotin(IV) monohydrate, [SnCl4(H2O)2]·H2O, and diaquatetrachlorotin(IV) dihydrate, [SnCl4(H2O)2]·2H2O, are reported and shown to contain the cis-[SnCl4(H2O)2] species and water mol­ecules in both cases. The trihydrate contains chains of the tin species linked by a single hydrogen-bonded water mol­ecule, whilst the tetrahydrate has a three-dimensional network. In addition, there are O—H…Cl interactions present.

Document Type: Research Article


Publication date: 2004-04-01

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