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Mg2Na2V10O28·20H2O and Mg3V10O28·28H2O

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The crystal structures of dimagnesium disodium decavanadate icosahydrate, Mg2Na2V10O28·20H2O, (I), and trimagnesium decavanadate octacosahydrate, Mg3V10O28·28H2O, (II), have been determined by single-crystal X-ray diffraction. They crystallize with monoclinic (C2/c) and triclinic ( ) symmetry, respectively. All the Mg2+ cations in (I) and (II) are octahedrally coordinated by six water mol­ecules. The Na+ cations in (I) are coordinated by three water mol­ecules and three O atoms of the decavanadate anions, and link the latter into a three-dimensional network. The decavanadate anions in (II) are not linked to one another.

Document Type: Research Article


Publication date: 2004-04-01

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