Skip to main content

Two novel Zn‐MOFs: structures and characterization

Buy Article:

$43.00 plus tax (Refund Policy)

Two novel three‐dimensional Zn‐MOFs (zinc metal‐organic frameworks), Zn53‐OH)(BTC)3(Phen)4·5H2O (denoted as HUT‐11) and Zn44‐O)(BTC)2(Phen)2·4H2O (denoted as HUT‐12), have been synthesized by metal–ligand‐directed assembly under hydrothermal conditions. Here, BTC and Phen are denoted as 1,3,5‐benzenetricarboxylate and phenanthroline. HUT‐11 contains two kinds of secondary building units (SBUs), Zn33‐OH)(COO)5 clusters and Zn2(COO)4 clusters. This material exhibits a new three‐dimensional (3,4,5)‐connected topology with the Schläfli symbol (4·6·8)2(4·82)(4·64·85)(42·62·82). Two perpendicular planes cross at five coordinated Zn1—Zn3—Zn5 nodes, giving a new three‐dimensional network. HUT‐12 is composed of Zn44‐O)(COO)6 clusters as the secondary building units and displays a two‐dimensional (3,6)‐connected TiS2 related net topology with the Schläfli symbol (42·6)(44·62·88·10). Both MOFs show blue light emission and a high thermal stability above 673 K.
No References
No Citations
No Supplementary Data
No Data/Media
No Metrics

Document Type: Research Article

Publication date: 2012-04-01

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more