Dyes derived from 1,4‐naphthoquinone as initiators for radical and cationic photopolymerisation

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Several 2‐phenylamino‐1,4‐naphthoquinone‐based dyes and two related benzo[2,3‐b]–phenazines were synthesised and characterised by proton nuclear magnetic resonance spectroscopy and electron ionisation mass spectrometry. The electrochemical and spectral properties of these compounds were investigated. The synthesised dyes were found to be capable photosensitisers for radical (reducible/oxidisable) and cationic polymerisations, respectively. In radical polymerization, better results in the oxidisable process were achieved.

Document Type: Research Article

DOI: http://dx.doi.org/10.1111/j.1478-4408.2012.00391.x

Affiliations: Institute of Polymer and Dye Technology, Technical University of Lodz, Stefanowskiego 12/16, 90-924 Lodz, Poland

Publication date: October 1, 2012

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