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Copper‐Catalyzed Decarboxylation of Aromatic Carboxylic Acids: En Route to Milder Reaction Conditions

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Abstract:

Abstract

The copper‐catalyzed decarboxylation of carboxylic aromatic acids has been advantageously achieved by using aliphatic amines like tetramethylethylenediamine (TMEDA) or hexamethylenetetraamine (HMTA) as ligands instead of the aromatic heterocyclic amines (quinoline, phenanthroline) used until now. The improvement is significant since the reaction can be performed at a lower temperature (ca. 50 °C less) and the reaction time is clearly shorter (15 min instead of 12 to 24 h).

Document Type: Research Article

DOI: http://dx.doi.org/10.1002/adsc.201201018

Affiliations: 1: Chimie ParisTech, UMR CNRS 7223, 11 rue Pierre et Marie Curie, 75005 Paris France 2: Université Paris 13, UMR CNRS 7224, 74 rue Marcel Cachin, 93017 Bobigny, France

Publication date: March 11, 2013

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