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Palladium‐Catalyzed Direct Denitrogenative C‐3‐Arylation of 1

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Abstract:

Abstract

A novel palladium‐catalyzed approach to direct C‐3‐arylation of 1H‐indoles with arylhydrazines using air as the oxidant via CN bond cleavage has been developed. Various substituents are tolerated in this system in moderate to good yields. This reaction could also be compatible with a larger scale. Thus, this strategy using arylhydrazines as arylating reagents provides a powerful method for constructing substituted 3‐aryl‐1H‐indoles.

Document Type: Communications

DOI: http://dx.doi.org/10.1002/adsc.201200997

Affiliations: State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Gansu Lanzhou, 730000, People's Republic of China and Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, Lanzhou 730000, People's Republic of China, Fax: +(86)-931-891-2582

Publication date: March 11, 2013

bpl/adsc/2013/00000355/00000004/art00019
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