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Phosphine‐Free Palladium‐Catalyzed Decarboxylative Coupling of Alkynylcarboxylic Acids with Aryl and Heteroaryl Halides

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Abstract:

Abstract

We herein report the design and development of a carboxyamido/carbene ligand and its Pd‐complex for the decarboxylative coupling of alkynylcarboxylic acids with aryl and heteroaryl halides to afford arylalkynes.

Document Type: Communications

DOI: http://dx.doi.org/10.1002/adsc.201200876

Affiliations: 1: I & PC Division, CSIR – Indian Institute of Chemical Technology, Hyderabad – 500607, India, Fax: : (+91)-40-271-93510; phone: (+91)-40-271-93510 2: Institut für Anorganische Chemie, Technische Universität, Bergakademie Freiberg, D-09596 Freiberg, Germany 3: Advanced Materials & Industrial Chemistry Group, School of Applied Sciences, RMIT University, Melbourne, Australia

Publication date: March 11, 2013

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