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Synthesis of Chiral Amino Acid Anilides by Ligand‐Free Copper‐Catalyzed Selective

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Abstract:

Abstract

An atom‐economic, practical and cost‐effective protocol for synthesis of chiral amino acid anilides via ligand‐free copper‐catalyzed selective CN cross coupling of chiral amino acid amides and aryl halides, hetereoaryl halides and a vinyl bromide has been developed. No racemization occurred during the CN coupling. A plausible mechanism is proposed.

Document Type: Communications

DOI: http://dx.doi.org/10.1002/adsc.201200752

Affiliations: 1: Institute of Green Catalysis and Synthesis, College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, People's Republic of China, Fax: (+86)-28-8407-9074 2: Department of Chemistry and Environmental Science, Zhangzhou Normal University, Zhangzhou 363000, People's Republic of China

Publication date: March 11, 2013

bpl/adsc/2013/00000355/00000004/art00016
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