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Synthesis of Chiral Amino Acid Anilides by Ligand‐Free Copper‐Catalyzed Selective

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An atom‐economic, practical and cost‐effective protocol for synthesis of chiral amino acid anilides via ligand‐free copper‐catalyzed selective CN cross coupling of chiral amino acid amides and aryl halides, hetereoaryl halides and a vinyl bromide has been developed. No racemization occurred during the CN coupling. A plausible mechanism is proposed.
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Document Type: Communications

Affiliations: 1: Institute of Green Catalysis and Synthesis, College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, People's Republic of China, Fax: (+86)-28-8407-9074 2: Department of Chemistry and Environmental Science, Zhangzhou Normal University, Zhangzhou 363000, People's Republic of China

Publication date: 2013-03-11

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