Skip to main content

Rhodium‐Catalyzed Asymmetric Hydroformylation of 1,1‐Disubstituted Allylphthalimides: A Catalytic Route to β

Buy Article:

$43.00 plus tax (Refund Policy)

Abstract

The high enantioselective rhodium‐catalyzed hydroformylation of 1,1‐disubstituted allylphthalimides has been developed. By employing chiral ligand 1,2‐bis[(2S,5S)‐2,5‐diphenylphospholano]ethane [(S,S)‐Ph‐BPE], a series of β3‐aminoaldehydes can be prepared with up to 95% enantioselectivity. This asymmetric procedure provides an efficient alternative route to prepare chiral β3‐amino acids and alcohols.
No References
No Citations
No Supplementary Data
No Article Media
No Metrics

Document Type: Communications

Affiliations: 1: Department of Chemistry and Chemical Biology and Department of Pharmaceutical Chemistry, Rutgers The State University of New Jersey, Piscataway, NJ 08854, USA, Fax: (+1)-732-445-6312 2: College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, People's Republic of China

Publication date: 2013-03-11

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more