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Palladium‐Catalyzed Decarboxylative Acylation of

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Abstract

A palladium‐catalyzed oxidative acylation of O‐phenyl carbamates with α‐oxocarboxylic acids via selective aromatic CH bond activation is described. This protocol represents the first ortho‐acylation of phenol derivatives, and a catalytic amount of triflic acid additive is crucial for this transformation.
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Document Type: Communications

Affiliations: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea, Fax: (+82)-31-292-8800

Publication date: 2013-03-11

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