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Palladium‐Catalyzed Decarboxylative Acylation of

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Abstract:

Abstract

A palladium‐catalyzed oxidative acylation of O‐phenyl carbamates with α‐oxocarboxylic acids via selective aromatic CH bond activation is described. This protocol represents the first ortho‐acylation of phenol derivatives, and a catalytic amount of triflic acid additive is crucial for this transformation.

Document Type: Communications

DOI: http://dx.doi.org/10.1002/adsc.201200993

Affiliations: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea, Fax: (+82)-31-292-8800

Publication date: March 11, 2013

bpl/adsc/2013/00000355/00000004/art00012
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