Skip to main content

Green and Scalable Aldehyde‐Catalyzed Transition Metal‐Free Dehydrative

Buy Article:

$51.00 plus tax (Refund Policy)

Abstract:

Abstract

In contrast to the borrowing hydrogen‐type N‐alkylation reactions, in which alcohols were activated by transition metal‐catalyzed anaerobic dehydrogenation, the addition of external aldehydes was accidentally found to be a simple and effective protocol for alcohol activation. This interesting finding subsequently led to an efficient and green, practical and scalable aldehyde‐catalyzed transition metal‐free dehydrative N‐alkylation method for a variety of amides, amines, and alcohols. Mechanistic studies revealed that this reaction most possibly proceeds via a simple but interesting transition metal‐free relay race mechanism.

Document Type: Communications

DOI: https://doi.org/10.1002/adsc.201200881

Affiliations: College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, People's Republic of China, phone: (+86)-138-577-45327, Fax: (+86)-577-8668-9300

Publication date: 2013-01-14

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more