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Aerobic Dehydrogenative Heck Reactions of Heterocycles with Styrenes: A Negative Effect of Metallic Co‐Oxidants

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Abstract:

Abstract

The aerobic dehydrogenative Heck reaction (DHR) of heterocycles with styrenes was found to be more efficient in the absence of metallic co‐oxidants. According to a study of the isotope effect, the CH cleavage was the rate‐determining step of the catalytic cycle. Electrospray ionization mass spectrometry, subsequent MS/MS, and high‐resolution mass spectrometry were used to detect and characterize catalytic intermediates and species formed in the presence of metallic co‐oxidants.

Document Type: Communications

DOI: https://doi.org/10.1002/adsc.201200787

Affiliations: Institut de Chimie Moléculaire de Reims РUMR 7312 CNRS РUniversité de Reims Champagne-Ardenne UFR des Sciences Exactes et Naturelles, BP 1039, 51687 Reims Cedex 2, France, Fax: (+33)-3-2691-3166

Publication date: 2013-01-14

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