Aerobic Dehydrogenative Heck Reactions of Heterocycles with Styrenes: A Negative Effect of Metallic Co‐Oxidants

$48.00 plus tax (Refund Policy)

Download / Buy Article:

Abstract:

Abstract

The aerobic dehydrogenative Heck reaction (DHR) of heterocycles with styrenes was found to be more efficient in the absence of metallic co‐oxidants. According to a study of the isotope effect, the CH cleavage was the rate‐determining step of the catalytic cycle. Electrospray ionization mass spectrometry, subsequent MS/MS, and high‐resolution mass spectrometry were used to detect and characterize catalytic intermediates and species formed in the presence of metallic co‐oxidants.

Document Type: Communications

DOI: http://dx.doi.org/10.1002/adsc.201200787

Affiliations: Institut de Chimie Moléculaire de Reims РUMR 7312 CNRS РUniversité de Reims Champagne-Ardenne UFR des Sciences Exactes et Naturelles, BP 1039, 51687 Reims Cedex 2, France, Fax: (+33)-3-2691-3166

Publication date: January 14, 2013

Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more