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Non‐Enzymatic Geometry‐Selective Acylation of Tri‐ and Tetrasubstituted α,α′‐Alkenediols

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Abstract

A highly geometry‐selective organocatalytic acylation of tri‐ and tetra‐substituted 2‐alkylidene‐1,3‐propanediols has been developed. The highly E‐selective acylation of various tetrasubstituted 2‐alkylidene‐1,3‐propanediols was achieved in 96 to >99% selectivity for the first time by a non‐enzymatic protocol.
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Document Type: Research Article

Affiliations: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan, phone: (+81)-774-38-3190, Fax: (+81)-774-38-3197

Publication date: 2012-11-26

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