Non‐Enzymatic Geometry‐Selective Acylation of Tri‐ and Tetrasubstituted α,α′‐Alkenediols

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Abstract:

Abstract

A highly geometry‐selective organocatalytic acylation of tri‐ and tetra‐substituted 2‐alkylidene‐1,3‐propanediols has been developed. The highly E‐selective acylation of various tetrasubstituted 2‐alkylidene‐1,3‐propanediols was achieved in 96 to >99% selectivity for the first time by a non‐enzymatic protocol.

Document Type: Research Article

DOI: http://dx.doi.org/10.1002/adsc.201200242

Affiliations: Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan, phone: (+81)-774-38-3190, Fax: (+81)-774-38-3197

Publication date: November 26, 2012

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