Skip to main content

Rhodium‐Catalyzed Asymmetric 1,4‐Additions, in Water at Room Temperature, with In‐Flask Catalyst Recycling

Buy Article:

$51.00 plus tax (Refund Policy)

Abstract:

Abstract

Using the newly introduced designer surfactant polyethylene glycol ubiquinol sebacate (PQS), as the platform for micellar catalysis, non‐racemic BINAP has been covalently attached and rhodium(I) inserted to form PQS‐BINAP‐Rh. This species, the first example of a non‐racemically‐ligated transition metal catalyst‐tethered amphiphile, can be utilized for Rh‐catalyzed asymmetric conjugate addition reactions of arylboronic acids to acyclic and cyclic enones. These are performed in water at room temperature, while the catalyst can be recycled without its removal from water in the reaction vessel.

Document Type: Communications

DOI: http://dx.doi.org/10.1002/adsc.201200160

Affiliations: Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA 93106, USA, Fax: (+1)-805-893-8265

Publication date: November 26, 2012

bpl/adsc/2012/00000354/00000017/art00005
dcterms_title,dcterms_description,pub_keyword
6
5
20
40
5

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more