Gold(I)‐Catalyzed Regio‐ and Stereoselective 1,3‐Dipolar Cycloaddition Reactions of 1‐(1‐Alkynyl)cyclopropyl Oximes with Nitrones: A Modular Entry to Highly Substituted Pyrrolo[3,4‐

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Abstract:

Abstract

An efficient approach for the synthesis of highly substituted pyrrolo[3,4‐d][1,2]oxazepines has been achieved by gold(I)‐catalyzed 1,3‐dipolar cycloaddition reactions of 1‐(1‐alkynyl)cyclopropyl oximes with nitrones in good to excellent yields as a single diastereomer. A complete chirality transfer was observed in this transformation.

Document Type: Research Article

DOI: http://dx.doi.org/10.1002/adsc.201200288

Affiliations: Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 N. Zhongshan Road, Shanghai 200062, People's Republic of China, Fax: (+86)-021-6223-5039

Publication date: September 17, 2012

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