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Direct Catalytic Formation of Primary and Tertiary Amides from Non‐Activated Carboxylic Acids, Employing Carbamates as Amine Source

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Abstract:

Abstract

The operationally simple titanium(IV)‐ or zirconium(IV)‐catalyzed direct amidation of non‐activated carboxylic acids with ammonium carbamates generates primary, and tertiary N,N‐dimethyl‐substituted amides in good to excellent yields.

Document Type: Research Article

DOI: http://dx.doi.org/10.1002/adsc.201200436

Affiliations: Department of Organic Chemistry, the Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm Sweden, phone: (+46)-8-162-484, Fax: (+46)-8-154-908

Publication date: September 17, 2012

bpl/adsc/2012/00000354/00000013/art00027
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