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Brønsted Acid‐Promoted Divergent Reactions of Enaminones: Efficient Synthesis of Fused Pyrroles with Different Substitution Patterns

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Abstract:

Abstract

Brønsted acid‐promoted divergent approaches for the synthesis of multi‐functionalized fused pyrroles with different substituted patterns (44 examples) have been established. The divergent pathways were controlled by varying the charging sequence to give a series of new fused pyrroles selectively. The direct C(sp 3)S bond formation was achieved for the two‐step, one‐pot reaction.

Document Type: Research Article

DOI: http://dx.doi.org/10.1002/adsc.201200280

Affiliations: 1: School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu 221116, People's Republic of China, phone: (+86)-516-8350-0065, Fax: (+86)-516-8350-0065 2: School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou, Jiangsu 221116, People's Republic of China, phone: (+86)-516-8350-0065, Fax: (+86)-516-8350-0065

Publication date: September 17, 2012

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