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β‐Aryl Nitrile Construction

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Abstract:

Abstract

The palladium‐catalyzed decarboxylative benzylation of α‐cyano aliphatic carboxylate salts with benzyl electrophiles was discovered. This reaction exhibits good functional group compatibility and proceeds under relatively mild conditions. A diverse range of quaternary, tertiary and secondary β‐aryl nitriles can be conveniently prepared by this method.

Document Type: Research Article

DOI: https://doi.org/10.1002/adsc.201200383

Affiliations: Joint Laboratory of Green Synthetic Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei 230026, People's Republic of China

Publication date: 2012-09-17

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