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Synthesis of Aryl Carbamates

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Coupling of aryl halides with potassium cyanate takes place at 100–110 °C in alcohols under the catalysis of CuI (cuprous iodide) and 2‐(2,6‐dimethylphenylamino)‐2‐oxoacetic acid, affording the corresponding aryl carbamates with great diversity.
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Document Type: Communications

Affiliations: 1: Center of Drug Discovery, China Pharmaceutical University, Nanjing 210009, People's Republic of China 2: State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, People's Republic of China, Fax: (+86)-21-6416-6128

Publication date: 2012-09-17

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