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Rhodium‐Catalyzed Enantioselective Conjugate Addition of Arylboronic Acids to Dihydronitronaphthalenes

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A highly enantioselective (up to 91% ee) rhodium‐catalyzed asymmetric addition of arylboronic acids has been achieved leading to the challenging dihydro‐3‐nitronaphthalenes using one equivalent of phosphoramidite ligand to rhodium catalyst. A concise formal asymmetric synthesis of the dopamine D1 agonist, dihydrexidine was accomplished using the method.
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Document Type: Communications

Affiliations: 1: Department of Chemistry, Indian Institute of Technology Khargapur, Kharagpur – 721302, India, phone: (+91)-32-2228-3340, Fax: (+91)-32-2225-5303 2: TCG Life Sciences Ltd, Saltlake, Kolkata – 700091, India, Fax: (91)-33-2367-3058 3: Department of Chemistry, Guru Jambheshwar University of Science and Technology Hisar, Haryana 125001, India

Publication date: 2012-09-17

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