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Asymmetric Synthesis of β-Aminosulfones Via the Enantioselective Hydrogenation of the Corresponding β-Ketosulfones

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Abstract:

A series of β-aminosulfones were synthesized with high enantioselectivities via a new approach, which combines asymmetric hydrogenation of β-ketosulfones and Mitsunobu amination reaction of the corresponding β- hydroxysulfones with a significant high control of the stereochemistry.





Keywords: Catalysts; Mitsunobu amination; asymmetric hydrogenation; ruthenium; β-aminosulfones; β-hydroxysulfones

Document Type: Research Article

DOI: http://dx.doi.org/10.2174/157017808783955835

Publication date: April 1, 2008

More about this publication?
  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
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