Selective Deprotection of Bisulfite Addition Products by FeCl3·6H2O and Fe(NO3)3·9H2O Supported on Silica Gel Under Solvent-Free Conditions

Authors: Mohammadpoor-Baltork, Iraj; Mehdi Khodaei, Mohammad; Ahankar, Hamideh

Source: Letters in Organic Chemistry, Volume 3, Number 11, November 2006 , pp. 872-876(5)

Publisher: Bentham Science Publishers

Buy & download fulltext article:

OR

Price: $63.10 plus tax (Refund Policy)

Abstract:

FeCl3·6H2O and Fe(NO3)3·9H2O supported on silica gel efficiently catalyze deprotection of bisulfite addition products to their corresponding aldehydes and ketones at room temperature under solvent-free conditions. Chemoselective deprotection of bisulfite addition products can be successfully achieved in the presence of trimethylsilyl ethers, oximes, acylals and acetals.

Keywords: Bisulfite adducts; Fe(III) salts; deprotection; solvent-free; aldehydes and ketones

Document Type: Research article

DOI: http://dx.doi.org/10.2174/157017806779117120

Affiliations: 1: Department of Chemistry, Isfahan University, Isfahan, 81746-73441, Iran.

Publication date: 2006-11-01

More about this publication?
  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
Related content

Tools

Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content

Text size:

A | A | A | A
Share this item with others: These icons link to social bookmarking sites where readers can share and discover new web pages. print icon Print this page