Selective Deprotection of Bisulfite Addition Products by FeCl3·6H2O and Fe(NO3)3·9H2O Supported on Silica Gel Under Solvent-Free Conditions
Authors: Mohammadpoor-Baltork, Iraj; Mehdi Khodaei, Mohammad; Ahankar, Hamideh
Source: Letters in Organic Chemistry, Volume 3, Number 11, November 2006 , pp. 872-876(5)
Publisher: Bentham Science Publishers
Abstract:
FeCl3·6H2O and Fe(NO3)3·9H2O supported on silica gel efficiently catalyze deprotection of bisulfite addition products to their corresponding aldehydes and ketones at room temperature under solvent-free conditions. Chemoselective deprotection of bisulfite addition products can be successfully achieved in the presence of trimethylsilyl ethers, oximes, acylals and acetals.Keywords: Bisulfite adducts; Fe(III) salts; deprotection; solvent-free; aldehydes and ketones
Document Type: Research article
DOI: http://dx.doi.org/10.2174/157017806779117120
Affiliations: 1: Department of Chemistry, Isfahan University, Isfahan, 81746-73441, Iran.
Publication date: 2006-11-01
- Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
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- In this Subject: Organic Chemistry
- By this author: Mohammadpoor-Baltork, Iraj ; Mehdi Khodaei, Mohammad ; Ahankar, Hamideh

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