One-Pot Synthesis of β-Hydroxy-1,3-Dienes Via Allyltriphenylphosphonium Isomerization Under Mild Conditions(SUPPLEMENTARY MATERIAL)

Authors: Sellanes, Diver; Scarone, Laura; Manta, Eduardo; Wipf, Peter; Serra, Gloria

Source: Letters in Organic Chemistry, Volume 3, Number 4, April 2006 , pp. 309-312(4)

Publisher: Bentham Science Publishers

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Abstract:

Reaction of allyltriphenylphosphonium bromide and Garner's aldehyde in basic media provided β- hydroxy-1,3-dienes. Similar results are described for other aliphatic and aromatic aldehydes.





Keywords: 3-diene; Garner's aldehyde; Wittig reactions; allyltriphenylphosphonium; β-hydroxy-1

Document Type: Research Article

DOI: http://dx.doi.org/10.2174/157017806776114621

Affiliations: Department of Organic Chemistry, Facultad de Quimica, UDELAR, Av. General Flores 2124, CC 1157, Montevideo, Uruguay.

Publication date: April 1, 2006

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
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