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Efficient Solvent-Free Synthesis of Quinolines Promoted by BiCl3

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Poly-substituted quinolines are readily prepared in excellent yields via a Friedlander reaction of oaminoarylketone or o-aminoarylaldehyde with α-methylene ketones in the presence of BiCl3 under solventfree and thermal heating conditions.

Keywords: BiCl3; Friedländer reaction; Quinoline; o-aminoaryl ketones; solvent-free; α-methylene ketones

Document Type: Research Article


Affiliations: Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.

Publication date: April 1, 2006

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.

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