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New Vistas in Halogen/Metal Exchange Reactions: The Discrimination Between Seemingly Equal Halogens

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Regioselective halogen/lithium permutation reactions were carried out on polybrominated biaryls. Thus, highly functionalized, dissymetrically substituted biaryls become easily accessible on gram scale.

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Keywords: Complexation; chromatographic comparison; disproportionation; halogen; isoquinoline; polar organometallic methods

Document Type: Research Article

Affiliations: Laboratoire de Stereochimie associe au CNRS (UMR CNRS 7509), Universite Louis Pasteur (ECPM), 25 rue Becquerel, F - 67087 Strasbourg Cedex 2, France.

Publication date: 2006-02-01

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
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