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Stereoselective Total Synthesis of (+)-Sedamine

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A highly efficient stereoselective total synthesis of piperidine alkaloid (+)-sedamine has been described utilizing two regioselective ring opening reactions of epoxide with vinyl metallic reagent and a ring closing metathesis reaction as the key steps.

Keywords: (+)-sedamine; ADH; RCM; regioselective epoxide opening; vinylmetallic reagent

Document Type: Research Article

Affiliations: Natural Products Chemistry Division, Regional Research Laboratory, Jorhat 785 006, Assam, India.

Publication date: February 1, 2006

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.

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