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Facile Double Fries Rearrangement of Diesters Under Microwave Irradiation; Application to the Synthesis of a Biogenetically Rare Type of Natural Phenol

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Various diesters successfully undergo a double Fries rearrangement to afford the corresponding bis o-hydroxylaryl ketones, in the presence of AlCl3 under microwave irradiation.

Keywords: Aluminum chloride; Double Fries rearrangement; Microwave irradiation; o-Hydroxyl aryl ketones

Document Type: Research Article

Affiliations: Sharif University of Technology, Department of Chemistry, P. O. Box 11365-9516 Tehran, Iran.

Publication date: February 1, 2006

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.

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