Facile Double Fries Rearrangement of Diesters Under Microwave Irradiation; Application to the Synthesis of a Biogenetically Rare Type of Natural Phenol

Authors: Moghaddam, Firouz M.1; Porkaleh, Hamdollah1; Zali-Boeini, Hassan1

Source: Letters in Organic Chemistry, Volume 3, Number 2, February 2006 , pp. 123-127(5)

Publisher: Bentham Science Publishers

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Abstract:

Various diesters successfully undergo a double Fries rearrangement to afford the corresponding bis o-hydroxylaryl ketones, in the presence of AlCl3 under microwave irradiation.

Keywords: Double Fries rearrangement; Microwave irradiation; o-Hydroxyl aryl ketones; Aluminum chloride

Document Type: Research article

Affiliations: 1: Sharif University of Technology, Department of Chemistry, P. O. Box 11365-9516 Tehran, Iran.

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