Tetra-n-Propylammonium Perruthenate (TPAP) Catalyzed Aerobic Oxidation of Hydroxylamines to Nitrones
Authors: Cardona, Francesca1; Gorini, Lapo1; Goti, Andrea1
Source: Letters in Organic Chemistry, Volume 3, Number 2, February 2006 , pp. 118-120(3)
Publisher: Bentham Science Publishers
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Abstract:
A novel aerobic, environmentally friendly oxidation of hydroxylamines to nitrones catalyzed by tetra-n-propylammonium perruthenate (TPAP) is reported. Complete conversions and reasonable to excellent yields were obtained for cyclic hydroxylamines.Keywords: Oxidation; nitrogen containing compounds; environmentally friendly; oxygen; catalysis
Document Type: Research article
Affiliations: 1: Dipartimento di Chimica Organica "Ugo Schiff", Universita di Firenze, via della Lastruccia 13, I- 50019 Sesto Fiorentino (FI), Italy.
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