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Tetra-n-Propylammonium Perruthenate (TPAP) Catalyzed Aerobic Oxidation of Hydroxylamines to Nitrones

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A novel aerobic, environmentally friendly oxidation of hydroxylamines to nitrones catalyzed by tetra-n-propylammonium perruthenate (TPAP) is reported. Complete conversions and reasonable to excellent yields were obtained for cyclic hydroxylamines.

Keywords: Oxidation; catalysis; environmentally friendly; nitrogen containing compounds; oxygen

Document Type: Research Article

Affiliations: Dipartimento di Chimica Organica "Ugo Schiff", Universita di Firenze, via della Lastruccia 13, I- 50019 Sesto Fiorentino (FI), Italy.

Publication date: 2006-02-01

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
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