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4H-Thiopyran-1-Oxides. Photochemical Deoxygenation and Oxenoid Reactivity

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Upon UV-irradiation in chloroform solution, some of the 2,4,4,6-tetrasubstituted-4H-thiopyran-1-oxides underwent deoxygenation to give the corresponding 4H-thiopyrans in good yields together with the corresponding 4Hthiopyran- 1,1-dioxides as minor components. Moreover, in benzene as an aromatic solvent oxenoid functionalization was observed.

Keywords: 4H-Thiopyran-1-oxides; oxenoid functionalization; photodeoxygenation

Document Type: Research Article

Affiliations: Department of Chemistry, University of Tehran, P.O. Box 13145-143, Tehran, Iran.

Publication date: February 1, 2006

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.

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