Highlights in Organic Chemistry [ Synthetic Applications of Multi-Component Coupling Reactions Proceeding Via Bis-π-Allylpalladium Complexes ]

Author: Malinakova, Helena C.

Source: Letters in Organic Chemistry, Volume 3, Number 2, February 2006 , pp. 82-90(9)

Publisher: Bentham Science Publishers

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Abstract:

In this report, recently developed multi-component coupling reactions proceeding via symmetrical and unsymmetrical bis-π-allylpalladium complexes are reviewed. The transformations provided an efficient access to 1,7-octadienes, oxa- and aza-heterocycles, medium-size carbocycles, homoallylic alcohols and α,β- unsaturated-δ-lactones.

Keywords: electrophile; palladium-catalyzed process; allylstannanes; bisallylation; transformation; carbon-carbon bonds

Document Type: Research article

Affiliations: 1: Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045-7582, USA.

Publication date: 2006-02-01

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