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Arsole Aromaticity Revisited

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Abstract:

Using quantum chemical methodology, we reinvestigate the aromaticity of the much debated arsole, using the newly developed gauge-including magnetically induced currents (GIMIC) method. GIMIC provides a quantitative measure of the induced ring current strength, showing arsole to be moderately aromatic. Comparison is made with pyrrole, phosphole, and cyclopentadiene.

Keywords: aromaticity; arsenic; heterocycles; quantum chemistry; small ring systems

Document Type: Review Article

DOI: https://doi.org/10.2174/1570178054405968

Affiliations: Department of Chemistry, Laboratory for Instruction in Swedish, P. O. Box 55, FI-00014 University of Helsinki, Finland.

Publication date: 2005-08-01

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  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
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