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Gold-Catalyzed Coupling of Alkynes and Acyl Iminiums

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Abstract:

A gold-catalyzed direct addition of alkynes to active acyl iminium ion, which was generated in situ with an acid chloride, to afford a propargylamides in excellent yields.

Keywords: copper-catalyzed addition; copper-mediated coupling; diisopropylethylamine; enantioselective synthesis; propargyl amines; solid-phase mannich condensation

Document Type: Review Article

DOI: http://dx.doi.org/10.2174/1570178054405959

Affiliations: Department of Chemistry, McGill University, 801 Sherbrooke St. West, Montreal QC H3A 2K6, Canada;

Publication date: August 1, 2005

More about this publication?
  • Letters in Organic Chemistry publishes original letters on all areas of organic chemistry including synthesis, bioorganic, medicinal, natural products, organometallic, supramolecular, molecular recognition and physical organic chemistry. The emphasis is placed on publishing quality papers very rapidly. Letters are processed rapidly and take full advantage of the Internet technology both for the submission and the review of the manuscripts.
    The journal is essential reading for all organic chemists both in academia and industry.
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